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Syllabus
Introduction slides
Diels-Alder cascade
Stupidity in scientific research
Lecture 1: adamantyl cation
Lecture 4: Strain release in steroid oxidation
Grob fragmentation
Lecture 5: Jacobsen epoxide kinetic resolution
Jacobsen DKR
Non-linear Effects in asymmetric catalysis
Lecture 6: Metal-catalyzed epoxidation
Sharpless AE
Jacobsen AE
Shi AE
Lecture 7: Sharpless AD
Dauben rearrangement
Lecture 8: Felkin-Anh example
Lecture 9: Noyori reduction
1,2 chelation
Baldwin rules
Directed hydrogenation
Lecture 10: Alkene hydroamination
Alkyne hydrofunctionalization
Stryker's reagent
Grubbs modified Wacker reaction
Photoredox hydrofunctionalization
Lecture 11: Schöllkopf method
Seebach alkylation
HAT-type alkene hydrofunctionalization
Aldol with chiral aldehyde
Lecture 12: Evans oxazolidinone
Crimmins oxazolidinethiones
Lecture 13: Thiourea ionization
Cyclization in supramolecular catalyst
Johnson steroid synthesis
Lecture 14: SmI2 cyclization
5-exo-trig selectivity
Parker morphine synthesis
Baran decarboxylation/C–C coupling
Nicewicz decarboxylation
Boronic Acid Minisci Reaction
Lecture 15: Torquoselectivity
Silicon-directed Nazarov (Denmark)
Boger tropoloisoquinoline synthesis
Lecture 16: Boger pyridine annulation
Lecture 17: Intramolecular 1,3-dipolar cycloaddition reactions
Danheiser phenol synthesis
Paterno-Büchi allylic alcohols
Lecture 18: Anionic oxy-Cope accelerating effect
Claisen-Büchi example
Lecture 19: Ene-reaction (Oppolzer)
Overman THF synthesis (Prins reaction)
Lecture 20: Transition-metal-catalyzed C–H functionalization
Pd(II)-catalyzed C–H activation/C–C coupling
Innate vs guided C–H functionalization
Photoredox catalysis
Lecture 21: Schlosser modification
Still-Genari modification
Lecture 23: Radical retrosynthesis
Carpanone synthesis
Chain englerin A synthesis
